|
|
ATP + Isovalerate + CoA <=> diphosphate + AMP + isovaleryl-CoA
|
6.2.1.1
acetate---CoA ligase
6.2.1.44
3-(methylthio)propionyl---CoA ligase
|
–
–
|
| |
BRENDA:
BS428220
MetaCyc:
RXN-18446
|
|
|
|
dimethylallyl_diphosphate + deoxyhumulone <=> diphosphate + lupulone
|
2.5.1.137
2-acyl-4-prenylphloroglucinol 6-prenyltransferase
|
–
|
| |
MetaCyc:
RXN-18441
|
|
|
|
dimethylallyl_diphosphate + 3-methyl-1-[2,4,6-trihydroxy-3-(3-methylbut-2-en-1-yl)phenyl]propan-1-one <=> diphosphate + deoxyhumulone
|
2.5.1.137
2-acyl-4-prenylphloroglucinol 6-prenyltransferase
|
–
|
| |
BRENDA:
BS439500
MetaCyc:
RXN-7810
|
|
|
|
dimethylallyl_diphosphate + phloroisovalerophenone <=> diphosphate + 3-methyl-1-[2,4,6-trihydroxy-3-(3-methylbut-2-en-1-yl)phenyl]propan-1-one + H+
|
2.5.1.136
2-acylphloroglucinol 4-prenyltransferase
|
–
|
| |
BRENDA:
BS438324
MetaCyc:
RXN-7811
|
|
|
|
deoxyhumulone + O2 + reduced_acceptor <=> humulone + H2O + acceptor
|
1.14.99.M4
|
–
|
| |
MetaCyc:
RXN-7807
|
|
|
|
isovaleryl-CoA + malonyl-CoA + H+ <=> phloroisovalerophenone + CO2 + CoA
|
2.3.1.156
phloroisovalerophenone synthase
2.3.1.220
2,4,6-trihydroxybenzophenone synthase
|
–
–
|
| |
BRENDA:
BR29473
KEGG:
R05331
MetaCyc:
2.3.1.156-RXN
|
|
